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Heavy Metal Index

Occurrence and Risk Assessment of Pesticides, Phthalates, and Heavy Metal Residues in Vegetables from Hydroponic and Conventional Cultivation

Shanghai farm samples had lower reported lead and cadmium concentrations under hydroponic cultivation than conventional soil cultivation. The element-specific summaries combine four vegetables, while commodity-specific means combine lead with cadmium; neither split can be reconstructed into commodity-by-element concentrations from the preserved main paper.

Key numbers

SystemElementMean µg/kgMedianMaximumEDI µg/kg BW/dayTHQDetected %Paper exceedance %
hydroponicPb4.773.613.40.01920.0048168.60
hydroponicCd0.910.655.10.003670.0036746.510
conventionalPb49.136.42770.1980.049579.121.1
conventionalCd11.58.48330.04640.046481.320

Commodity-specific combined Pb+Cd means, conventional/hydroponic (µg/kg): lettuce 80.6/5.7; celery 51.3/3.2; cucumber 58.6/6.4; tomato 47.9/5.6. Soil lead (Pb)/cadmium (Cd): 13.02 ± 4.89 / 0.13 ± 0.02 mg/kg; hydroponic irrigation water: 0.036 ± 0.012 / 0.00017 ± 0.00008 mg/L (§3.3).

Methods (brief)

Fresh produce purchased directly from Shanghai farms in 2022–2023, vacuum freeze-dried for analysis. Pb and Cd measured by ICP-MS (Agilent 7500 CX); details refer to an earlier method. Means exclude results below LOQ (§2.5). Exposure model uses 242 g vegetables/day and 60 kg adult body weight. The preserved main PDF does not explicitly reconcile the reported concentration basis with freeze-dried preparation.

Implications

Supports a local cultivation-system comparison and the soil/irrigation pathway. It does not establish commodity-specific Pb or Cd distributions or universal hydroponic safety. Mixed-contaminant hazard indices include pesticides and phthalates; their interpretation remains source-reported.

Evidence Fitness: EF-2 for qualified comparative occurrence; EF-3 for the exposure model. Preserve summary statistics; require commodity-by-element data and basis clarification before narrower row admission.

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