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Heavy Metal Index

Determination of Trace and Heavy Metals in Fruit Juices in the Romanian Market

Overview

Bora and colleagues measured copper, zinc, nickel, chromium, cobalt, lead, cadmium and arsenic by ICP-MS in 42 commercial fruit juices from the Romanian market, grouped by fruit and by box or plastic bottle packaging. Results are means of three samples per group in µg/L. Apple juice had the highest lead.

Key numbers

  • Apple juice lead: 10.71 ± 1.35 µg/L (box) and 11.06 ± 1.92 µg/L (plastic) (Table 1, p. 127).
  • Cadmium was quantified only in apple, peach and mango juice, at most 0.36 ± 0.01 µg/L (peach, plastic) (Table 1, p. 127).
  • Arsenic was quantified only in apple (plastic, 0.16 ± 0.06 µg/L) and multifruit juice (0.19 and 0.17 µg/L) (Table 1, p. 127).
  • Pear juice lead, cadmium and arsenic were all below LOQ (Table 1, p. 127).

Methods (brief)

Half a millilitre of juice was microwave-digested with nitric acid and hydrogen peroxide, diluted to 50 mL and analysed on a Thermo iCAP Q ICP-MS with external calibration. LOQ values, CRMs and recoveries are not reported.

Evidence Fitness

Small groups (n=3) with no QA beyond replicates and per-litre units only. The juices are a proxy for sports-drink-bases, which is not measured or linked; they are direct for the named fruit juice pages.