Unuvar et al. 2017 - elements in commercial infant formulas

This study measured heavy metals, essential elements, and minerals in 20 commercial infant formula samples collected from pharmacies and supermarkets in Malatya, Turkey. The HMT&C-relevant values are Al and Pb in powdered formula, with Fe, Zn, Mg, Ca, K, and Na reported for nutritional context.

Key numbers

Age-group mean concentrations in infant formula (Table III; mean +/- SD):

Element0-6 months (n=10)7-12 months (n=10)
Al1.29 +/- 0.66 ug/g1.54 +/- 0.35 ug/g
Pb0.16 +/- 0.02 ug/g0.18 +/- 0.08 ug/g
Fe61.34 +/- 13.72 ug/g72.6 +/- 4.05 ug/g
Zn29.72 +/- 4.04 ug/g34.64 +/- 6.32 ug/g
Mg0.51 +/- 0.08 mg/g0.50 +/- 0.15 mg/g
Ca4.19 +/- 0.45 mg/g4.35 +/- 0.96 mg/g
K6.53 +/- 1.09 mg/g6.08 +/- 2.27 mg/g
Na0.95 +/- 0.19 mg/g1.89 +/- 0.75 mg/g

Source-reported method performance and exposure framing:

  • LOD/LOQ were 1.90/6.35 ug/g for Al, 0.01/0.02 ug/g for Pb, 0.33/1.12 ug/g for Fe, 0.16/0.53 ug/g for Zn, and 0.07/0.24 ug/g for Mg.
  • The paper states that none of the samples contained Al or Pb in amounts representing a health hazard for infants.
  • Calculated daily intake for 0-6 month infants was 19.4 ug/kg bw/day Al and 2.4 ug/kg bw/day Pb.
  • Calculated daily intake for 7-12 month infants was 23.1 ug/kg bw/day Al and 2.7 ug/kg bw/day Pb.

Methods (brief)

Twenty infant formula samples from five manufacturers were collected from pharmacies and supermarkets in Malatya, Turkey. Samples were dried at 105 C for 24 hours. About 0.50 g sample or NIST-SRM 8418 Wheat Gluten was microwave digested in Teflon vessels with 7 mL concentrated nitric acid and 1 mL hydrogen peroxide, then diluted to 25 mL. Al, Ca, Fe, K, Mg, Na, and Zn were measured by flame AAS and Pb by graphite furnace AAS using a PerkinElmer AAnalyst 800 system. Microwave digestion used a Milestone Start D closed-vessel system. Recoveries against NIST-SRM 8418 were 92% for Al, 87% for Ca, 93% for Fe, 89% for K, 97% for Mg, 96% for Na, 90% for Pb, and 91% for Zn.

Implications

Standards work: This is direct powdered infant formula occurrence evidence for Al and Pb in a Turkish retail sample set, split by age-labeled formula group.

Courses: Useful for showing how the same formula survey can support toxic-element screening and nutrient/mineral context without combining the two endpoints.

App: Provides powder-basis occurrence fields for Al and Pb in commercial infant formula, with Fe, Zn, Mg, Ca, K, and Na as nutritional context only.

Microbiome: Not addressed.

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Verification notes

  • Fresh auto-fetch ingest 2026-05-19 from the gap-driven infant-formula wishlist.
  • Strict brand firewall: this page reports manufacturer count and formula age groups, but does not name or rank commercial brands.
  • The paper reports total Pb and Al only; no arsenic, mercury, or chromium speciation issue applies.
  • Methods vendor/equipment/reference-material names are retained under Part 12 Exception 2.

Page history

The five most recent substantive edits to this page. The full version history lives in git; when DOI minting comes online (see schema docs), each entry below will also link to a version-pinned DataCite DOI.

CommitDateDescription
ce3e07c2026-05-28activation | Vercel DATACITE env slots set, curators.md filled with founder entry + six scoped reviewer invitations, peer-review onboarding playbook drafted
51400b92026-05-28audit-queue: gasparik2017-wild-boar-slovakia-metals audited-revised