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Heavy Metal Index

Assessment of Heavy Metal Contamination in Vegetables from Industrial Areas of Haryana

Overview

Rani and colleagues collected 111 samples of 19 vegetables from industrial areas of Haryana in the winter of 2017-18 and measured ten metals by atomic absorption on a dry-weight basis. Leafy vegetables, especially mustard and spinach, carried the most lead, cadmium and iron, and total hazard quotients exceeded 1 for every vegetable.

Key numbers

  • Mustard: lead 4.01 ± 3.81, cadmium 0.33 ± 0.14, chromium 6.39 ± 5.35 mg/kg dw (Table 2, p. 624).
  • Spinach: lead 1.57 ± 2.43, cadmium 0.47 ± 0.6 mg/kg dw (Table 2, p. 624).
  • Carrot: cadmium 0.325 ± 0.39 mg/kg dw, lead not detected; potato: lead 0.8 ± 0.05, cadmium not detected (Table 2, p. 624).

Methods (brief)

Washed vegetables were oven-dried at 60 °C, ground and digested with nitric, sulfuric and perchloric acids, then read by flame AAS. Triplicates, reagent blanks and a reference standard (within 5 percent of certified values) were used; no LOD is stated.

Evidence Fitness

Industrial-area sampling, so values are not typical of ordinary supply; one site used wastewater irrigation. Per-vegetable counts are small, and Table 2 prints n = 4 for every vegetable although Table 1 gives 3 to 15. Direct for non-root and root vegetables as raw produce; it is a proxy for root-vegetable-purees, which is not linked.