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Heavy Metal Index

Content of major and trace elements in raw ewes’ milk used for production of traditional white brined cheese

Levkov and colleagues measured major and trace elements in raw ewes’ milk from six regions in the Republic of Macedonia.

Overview

Levkov and colleagues measured major and trace elements in raw ewes’ milk from six regions in the Republic of Macedonia. This is direct dairy-occurrence evidence in wet-weight mg/kg units, with regional variation linked by the authors to differing anthropogenic pressures.

Key numbers

Table 2 reports trace-element concentrations in raw ewes’ milk, mg/kg wet weight. For the averaged regional rows, the source reports:

RegionAlBaCuFeMnSrZn
Sv. Nikole1.12 ± 0.270.21 ± 0.041.33 ± 0.141.86 ± 0.240.05 ± 0.010.92 ± 0.193.67 ± 0.66
Sasa1.30 ± 0.520.91 ± 0.611.00 ± 0.272.31 ± 1.310.09 ± 0.040.72 ± 0.224.44 ± 1.59
Veles1.58 ± 0.450.21 ± 0.031.07 ± 0.132.85 ± 0.310.06 ± 0.020.54 ± 0.154.99 ± 1.56
Mariovo1.11 ± 0.160.37 ± 0.050.76 ± 0.111.94 ± 0.590.07 ± 0.010.72 ± 0.133.76 ± 0.91

The single Bistra sample reports Al 2.26 mg/kg, Ba 0.382 mg/kg, Co 0.57 mg/kg, Cu 0.93 mg/kg, Fe 3.38 mg/kg, Mn 0.16 mg/kg, Ni 0.18 mg/kg, Sr 0.26 mg/kg, and Zn 3.89 mg/kg. Ag, As, Cd, and Pb were below the reported detection cutoffs in the tabulated samples.

The abstract reports major-element ranges of Ca 1131-2070 mg/kg, Mg 98.3-183 mg/kg, Na 223-400 mg/kg, and P 569-1080 mg/kg.

Methods (brief)

The authors collected raw ewes’ milk from households in Sv. Nikole, Sasa, Veles, Mariovo, Skopje, and Bistra. Seventeen elements were measured after microwave digestion by ICP-AES. Results are reported on a wet-weight basis and discussed against regional anthropogenic pressure, including mining and smelting influence.

Implications

Certification: This is direct dairy occurrence evidence, but the matrix is raw ewes’ milk rather than packaged consumer dairy products.

Courses: Useful case for showing how upstream mining and smelting context can appear in raw-milk trace-element profiles.

App: Context for dairy ingredient exposure patterns, especially for metals reported above detection in wet-weight milk.

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Verification notes

Recovered from skip:incomplete-metadata during the 2026-06-11 recovery fire. DOI was not visible in the extracted text, but the PDF contains direct wet-weight occurrence data for raw ewes’ milk and is in-scope lane a1 evidence.

Update history

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