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Heavy Metal Index

Selected Toxic Elements and Pesticide Residues in Organic and Conventional Honey from Poland: A Preliminary Comparative Study

Overview

Wilczyńska and colleagues measured lead, cadmium, total arsenic and zinc (and pesticide residues) in 15 Polish honeys from the 2025 season, 12 from certified organic apiaries and 3 from conventional apiaries, each analyzed in quadruplicate. Lead ranged from 17.19 to 644.34 µg/kg, and the authors report that seven of the twelve organic honeys were above the EU maximum of 100 µg/kg. The authors call the study preliminary and exploratory because the groups are small, unequal and not geographically matched.

Key numbers

  • Lead, highest single honey: 644.34 ± 51.81 µg/kg, organic sample 9 from a peri-urban apiary in Małopolska Province (Table 4, p. 8).
  • Lead, conventional honeys: 27.01, 22.90 and 75.64 µg/kg (Table 4, p. 8).
  • Arsenic, highest: 287.72 ± 19.97 µg/kg (sample 5) and 182.97 ± 9.18 µg/kg (sample 4), both from Podkarpackie Province (Table 4, p. 8).
  • Cadmium range 0.71 to 53.68 µg/kg (Section 3.1, p. 8).
  • All-sample summary in the intake table: lead mean 0.147 and maximum 0.644 mg/kg; arsenic mean 0.055 and maximum 0.387 mg/kg (Table 6, p. 10).

Methods (brief)

About 1.3 g honey was digested with nitric acid in a closed microwave system. Arsenic, cadmium and lead were measured by graphite furnace AAS with a palladium modifier, and zinc by flame AAS. Calibration used certified single-element standards. Each honey was analyzed four times and reported as mean ± SD.

Evidence Fitness

Fifteen honeys, one per apiary, so this is a small preliminary sample. The paper states no limit of detection, limit of quantification, certified reference material or recovery for any element, so accuracy cannot be checked. Table 6 gives an arsenic maximum of 0.387 mg/kg that conflicts with the Table 4 maximum of 287.72 µg/kg; both are recorded as printed and flagged. The seven-of-twelve lead exceedance count is the authors’ observation and is kept as a note, not as a finding. The organic versus conventional lead difference (p = 0.021) is confounded by geography, as the authors say. Botanical origin is not reported.