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Heavy Metal Index

Addendum to the Opinion SCCS/1489/12 on Zinc oxide (nano form), COLIPA S 76 (SCCS/1518/13)

The addendum widens the 2012 conditions.

The addendum widens the 2012 conditions. Nano zinc oxide of purity at least 96 % is covered, provided the impurities responsible for the lower purity are only carbon dioxide and water and any other impurities total less than 1 %. The median particle diameter must be above 30 nm (D1 above 20 nm). A 90-day inhalation study gave a NOAEL of 0.3 mg/m3, and SCCS does not recommend applications that lead to inhalation.

Key numbers

  • Conclusion (PDF p. 13): purity ≥ 96 %, wurtzite, rod-like, star-like or isometric clusters, impurities only CO2 and water, other impurities < 1 % in total; D50 > 30 nm and D1 > 20 nm; listed silane or dimethicone coatings or uncoated; water solubility below 50 mg/L.
  • Inhalation (PDF p. 13): 90-day NOAEL 0.3 mg/m3.
  • These conditions appear in Annex VI entry 30a of Regulation (EC) No 1223/2009.

Methods (brief)

Committee review of additional applicant data on a 96 %-purity material and of the inhalation study. Secretariat contact: SANCO-C2-SCCS@ec.europa.eu.

Evidence fitness

Supports the purity and impurity framework in EU law for nano zinc oxide. The “other impurities below 1 %” condition is a total, not a lead or cadmium limit: 1 % equals 10,000 mg/kg, far above any element-specific impurity value in this collection.

Limitations

No analytical impurity profile by element. Applies to the nano form only.

Update history

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