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Heavy Metal Index

Effect of transitional nutrition in intake level of heavy metal from Iranian sauces consumption and its carcinogenic and health risks

Overview

The authors measured lead, chromium, manganese, aluminum, copper, zinc and iron by MP-AES in 60 commercial mayonnaise and ketchup samples from the Iranian market, grouped by packaging (glass, plastic, sachet), and modeled intake under three diet scenarios. Average lead was 0.67 µg/g in mayonnaise and 0.51 µg/g in ketchup, several times the 0.1 mg/kg reference levels the authors cite. Cadmium and arsenic were not measured.

Key numbers

  • Mayonnaise lead: 0.68 (SD 0.11) mg/kg glass-packed, 0.64 (0.16) plastic-packed, 0.69 (0.07) sachet-packed (Table 3).
  • Ketchup lead: 0.54 (SD 0.09) mg/kg plastic-packed, 0.48 (0.06) sachet-packed (Table 3).
  • Chromium: 0.24 to 0.64 mg/kg across groups; aluminum 0.65 to 1.70 mg/kg (Table 3).

Methods (brief)

Half a gram of sauce was digested with nitric acid and hydrogen peroxide on a hot plate and analyzed in triplicate by Agilent 4210 MP-AES. The lead LOD was 0.032 mg/kg and the LOQ 0.107 mg/kg. Spike recoveries at 50 mg/kg were 92 to 104 percent; no certified reference material is reported.

Evidence Fitness

A reasonable sample design (four brands, three production series per packaging type), but collection dates are not given, and the 50 mg/kg spike is far above measured levels. The text swaps the sauce labels for the highest zinc and lowest manganese compared with Table 3; findings follow the table. Mayonnaise and ketchup are measured directly here. They are only proxies for ranch-dressing, ranch-dressing-low-calorie, barbecue-sauce, pasta-sauce and brown-gravy, which are not linked.