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Heavy Metal Index

Lead in bottled waters: contamination from glass and comparison with pristine groundwater

Shotyk and Krachler measured total lead in bottled waters from 125 brands across 28 countries.

Shotyk and Krachler measured total lead in bottled waters from 125 brands across 28 countries. Excluding glass bottles, the median was 8.5 ng/L (n = 185), with a range from less than 1 to 761 ng/L. Twenty-five Canadian brands had a median of 15.9 ng/L (n = 25), range 2.1 to 268 ng/L. Pristine Ontario groundwater had a median of 5.1 ng/L (n = 18). This paper was also processed by Codex locally and is ingested here for cross-check.

Key numbers

The text layer prints an opening parenthesis where a plus-minus sign belongs, and a closing parenthesis where an equals sign belongs. The table below records the scientific reading. The ledger keeps the text-layer token.

Glass versus PET for three coded brands, ng/L lead:

CodeGlassPETRatio glass/PET
A227 ± 111 (n = 6)4.0 ± 1.6 (n = 5)56.8
B261 ± 43 (n = 6)8.7 ± 3.3 (n = 6)30
C154 ± 66 (n = 6)5.9 ± 3.7 (n = 6)26.1

The prose states that glass contained about 57, 30, and 26 times more lead than the matching PET. A footnote on bottle glass, measured by XRF, reports one bottle at 3 mg/kg lead and the others at 114 to 267 mg/kg. That is container glass, not the water. The detection limit for lead in water is given as 1 ng/L. SLRS-4 measured 88 ± 5 ng/L (n = 25) against a certified 86 ± 7 ng/L. The acid blank is about 800 pg/L, contributing about 0.8 pg/L to the sample.

The authors cite a maximum acceptable concentration of 10 µg/L used by the EU, Health Canada, and WHO. That cited limit is not a result of this survey.

Methods (brief)

Lead in water was measured by ICP-SMS after acidification. Container type is part of the result: glass, PET, and other packaging are not pooled in the headline median. The median of 8.5 ng/L excludes glass. Brand names are not used here. The three paired products are codes A, B, and C.

Evidence fitness

The measurements support total lead in bottled drinking water, with a strong container effect from glass. They do not support a mineral-water subclass, a brand ranking, or a lead-species split.

Limitations

The text layer substitutes parentheses for plus-minus and equals signs. Ratios in the table confirm the paired readings. The Canadian median is a subset, not the world median. The 10 µg/L figure is a cited regulatory maximum, three orders of magnitude above the medians in this paper, and it is not a measured concentration.

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