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Heavy Metal Index

ICP-MS determination of trace metals in commercial cornflakes from the UAE market

Overview

Sayegh and colleagues bought 40 cornflake products at retail outlets in the United Arab Emirates in summer 2022 and measured 13 elements by ICP-MS. Mean lead was 353.4 ug/kg, with every product at or above 296.6 ug/kg; mean arsenic was 80.5, cadmium 35.2 and mercury 5.0 ug/kg. Product category made little difference, except that natural-flavored products had more lead than chocolate-flavored ones. The PDF is the accepted manuscript (article in press).

Key numbers

  • Lead mean 353.44 ± 62.49 ug/kg, range 296.62 to 563.65 (Table 5).
  • Total arsenic mean 80.53 ± 98.43 ug/kg, range 11.87 to 572.95; cadmium mean 35.18 ± 9.64, range 17.79 to 66.12 (Table 5).
  • Lead median 320.44 ug/kg in chocolate-flavored vs 363.18 in natural-flavored products, p = 0.03 (Table 7).

Methods (brief)

Microwave digestion of 0.5 g ground cereal in nitric acid, hydrogen peroxide and hydrochloric acid; ICP-MS in helium collision mode following EPA 6020B; triplicate measurements. Accuracy checked with rice flour (IRMM-804) and fortified breakfast cereal (SRM 3233) reference materials, with lead recovery 109 percent; spike recoveries 94 to 102 percent.

Evidence Fitness

A good-sized retail sample with reference-material QA, but internal inconsistencies weaken it: unit labels switch between mg/kg and ug/kg, the stated exceedance shares cannot be reproduced from the per-product table, and lead shows an unusual floor near 300 ug/kg in all 40 products. Accepted manuscript, not the final version. For crisped-rice-cereal this is a proxy: cornflakes are a corn-based breakfast cereal and no crisped rice product was measured.