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Heavy Metal Index
Soil sampling equipment illustrating geochemical characterization near gold mine tailings.

Geochemical assessment of soil and water around abandoned gold mine tailings dams: evidence from the Welkom Goldfield, South Africa

Overview

Makhadi and colleagues characterize potentially toxic element (PTE) contamination in soil and surface water around abandoned gold mine tailings dams in the Welkom Goldfield, Free State, South Africa. Gold is the mining context; the paper does not measure gold concentrations in soil or water. The measured analytes are arsenic (As), cadmium (Cd), chromium (Cr), Cu, lead (Pb), uranium (U), and Zn. Geoaccumulation indices and enrichment factors are computed to characterize contamination severity. This is a soil and water environment study, not a food occurrence study.

Key numbers

Soil PTE means across sites (mg/kg) include As approximately 18 to 34 depending on site, with geoaccumulation indices flagging As, Cr, and U as moderately to heavily contaminated at certain locations. Pb and U ranged from unpolluted to strongly contaminated based on comparisons with regional background and prior Witwatersrand Basin studies (Table S10, pp. 10 to 11). Anions including sulfate, bicarbonate, chloride, and fluoride were also characterized in water samples. LOD and LOQ values for the analytical method are reported on p. 5.

Methods summary

ICP-MS analysis for PTEs in soil and water matrices. Geoaccumulation index and enrichment factor calculations applied. Sampling sites distributed across the Welkom Goldfield area. The analytical method uses LOD/LOQ separation from solid residue.

Implications for the wiki

This paper supports Arsenic, Total, Lead, Chromium, and Uranium with soil environment data from the South African gold mining belt. It reinforces the finding from Okereafor et al. (2019) that abandoned gold mine tailings in South Africa generate PTE contamination plumes in surrounding soil. No food occurrence data are provided.

Update history

No substantive edit history is available in this build. The full commit record is available in git.