Overview
This source page is a mechanical bulk-ingest record for a PDF in the research-pulls corpus. It preserves source-level identity, routeable product/analyte scope, and exact extracted numeric lines for later human or fresh-context audit. It does not derive HMTc thresholds, percentiles, or brand-by-brand comparisons.
Key numbers
The worker extracted the full PDF text with layout preservation twice and compared extraction hashes before commit. The following lines are copied from numeric/table-bearing regions of the PDF and retain the source units and wording where legible:
- c.4290206. phosphate analogue arsenate (AsO2 4 or Asi) over a range of
- Table 1. Different classes of PASA. 3
- anchors with biomolecules (table 1). The same sites also behaved as leaving groups during
- 1B and 2 is presented in tables 2 – 4, respectively. Although the tabular data shows differences among
- Table 2. Geometrical values of the Class 1A modelled compounds obtained from M06-2X 6-31þG(2d,2p) computation (R,
- Table 3. Geometrical values of the Class 1B modelled compounds obtained from M06-2X 6-31þG(2d,2p) computation.
- Table 4. Geometrical values of the Class 2 modelled compounds obtained from M06-2X 6-31þG(2d,2p)/AMBER computation. 8
- Table 5. Values of rate constant (k) (in s21) for the hydrolysis of As/P-esters belonging to different classes.
- times more stable in monoanionic diester form than in dianionic monoester variants of Class 1B,
- hydrolysis compared to PASA of Class 1A and 1B, it is still a kinetically unstable molecule, and
Methods (brief)
- Analytical method details were not mechanically resolved from extracted text.
Implications
This page makes the source discoverable for category-level evidence routing. Values remain source-native and should be used only with the stated matrix, species, basis, geography, and censoring context from the paper. The page does not convert total mercury to methylmercury or use total arsenic as inorganic arsenic.
Wiki pages this source may touch
Verification notes
- Identity check: DOI, raw handle, candidate cite-key, and SHA-256 were compared against existing
wiki/sources/pages before creation. - Full-PDF read:
pdftotext -layoutwas run on the full PDF twice; extracted text hashes matched before the page was written. - Numeric verification: numeric/table-bearing lines were selected mechanically from the verified extraction and preserved without unit conversion or rounding.
- Brand firewall: the worker skips PDFs when extracted numeric lines appear brand/manufacturer-sensitive; this page contains category-level or species-level evidence only.
- HMTc firewall: no threshold, percentile, pass/fail, clean/dirty, or certification math is stated.
Update history
The five most recent substantive edits to this page, classified major (evidence or structure moved), correction (a published value or statement was wrong and has been fixed), or minor (narrative rewritten without changing the underlying evidence). Each description is derived from what the edit did to this page; the linked commit is the authoritative record, routine regeneration passes are excluded, and the full version history lives in git. When DOI minting comes online (see schema docs), each entry below will also link to a version-pinned DataCite DOI.