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Heavy Metal Index

Heavy Metal Determinations in Some Selected Chocolates Marketed in Nigeria

Overview

Sani and colleagues bought four chocolate brands in Hadejia, dried and digested them, and measured lead, cadmium, chromium and nickel by flame atomic absorption. Table 1 reports one value per brand and metal, labeled in mg/g. The authors conclude that all samples exceed WHO values for lead, cadmium and chromium.

Key numbers

  • Lead 0.05 to 0.17 “mg/g”, cadmium 0.03 to 0.05 “mg/g”, chromium 0.28 to 0.65 “mg/g”, nickel 0.06 to 0.10 “mg/g” (Table 1, p. 1543).
  • Taken at face value, the lead unit means 50 to 170 mg/kg, which is implausible for chocolate; the true unit cannot be determined from the paper.

Methods (brief)

Samples were oven-dried at 70 °C, ground, and about 1.5 g was digested on a hot plate in nitric acid and hydrogen peroxide, then read by flame atomic absorption. A reagent blank was run; no detection limits, reference materials or recoveries are reported.

Evidence Fitness

Very weak: four products, one supermarket, no quality control, and a unit label that cannot be reconciled with plausible chocolate levels. All findings carry an integrity flag and no converted value. Chocolate is a proxy for chocolate pudding and chocolate nut candy, which are not linked.