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Heavy Metal Index

Cerium occurs as cerium-phosphate clusters around bioapatite nanocrystals in deep-sea sediments

Using high-energy-resolution X-ray absorption spectroscopy, electron microscopy and computer modeling, this geochemistry study found that cerium in deep-sea mud sits in cerium-phosphate clusters in an amorphous layer around fish-bone apatite nanocrystals, rather than inside the crystal lattice. It is a mineral speciation study with no food-chain component.

Key numbers

  • Two sediment samples from the Clarion-Clipperton Zone contained 2203 plus or minus 545 mg/kg and 2081 plus or minus 414 mg/kg cerium (p. 2).

Methods (brief)

Synchrotron X-ray absorption spectroscopy, transmission electron microscopy and density functional calculations on deep-sea sediment and reference minerals.

Evidence fitness

Off-topic for dietary exposure: it informs where cerium resides in marine sediments of interest for rare earth resources and does not support food, exposure or toxicity statements.

Limitations

Two sediment samples; geochemical focus only.

Update history

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