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Heavy Metal Index

Determination of metal(oids) in different traditional flat breads distributed in Isfahan city, Iran: Health risk assessment study by latin hypercube sampling

Overview

Khodaei and colleagues measured lead and cadmium by graphite furnace AAS, arsenic and mercury by hydride AAS and eight other elements by ICP-OES in 93 barbari, lavash and tafton breads from 93 Isfahan bakeries, and simulated health risks with Latin hypercube sampling. Tables 2 and 3 give minimum, maximum and mean ± SD on a dry-weight basis, overall and per bread type.

Key numbers

  • All breads: lead 0.24 ± 0.11 mg/kg (range 0.01 to 0.46), cadmium 0.01 ± 0.006, arsenic 0.03 ± 0.004, mercury 0.01 ± 0.008 mg/kg (Table 2).
  • Barbari: lead 0.36 ± 0.04 mg/kg; lavash 0.25 ± 0.02; tafton 0.1 ± 0.04 mg/kg (Table 3).
  • Aluminum averaged 29.88 ± 8 mg/kg (Table 2).

Methods (brief)

Bread was oven-dried at 50 °C for 48 hours and digested in duplicate by microwave with nitric acid, hydrochloric acid and hydrogen peroxide. ICP-OES recoveries were 92 to 102% (Table 1); detection limits for the AAS elements are not tabulated and no certified reference material is named.

Evidence Fitness

A reasonably sized bakery survey (one sample per bakery) with dry-weight results. Overall extremes in Table 2 do not match the per-type extremes in Table 3 for arsenic, lead, zinc and mercury, and these are flagged. Arsenic and mercury are totals. Leavened flat breads are a proxy only for chapattis, doughnut, pie-crust, wheat-cereal-biscuits and white-cake, which are not linked. One manifest row called this paper abstract only, but the full published PDF was read.