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Heavy Metal Index

Quantitative Analysis of Heavy Metals in Unbranded Whitening Creams Sold in Karachi

Overview

Alamgir and colleagues measured lead, nickel, chromium, total arsenic, and copper in 25 unbranded skin-whitening creams sold in Karachi, Pakistan. Lead was the highest-concentration contaminant in the sample set, and every sampled cream exceeded the paper’s cited 1 ppm lead limit for cosmetics. The source is direct occurrence evidence for unbranded whitening-product matrices.

Key numbers

Table I reports concentrations in ppm for 25 skin-whitening cream samples.

MetalMeanMin-maxSD
lead (Pb)4.5682.11-9.121.847
nickel (Ni)0.5460.12-1.210.274
chromium (Cr)2.0131.13-2.680.421
arsenic (As)0.0220.005-0.0910.021
Cu0.4890.22-0.850.145

The highest lead value was 9.12 ppm and the lowest was 2.11 ppm. Chromium ranged from 1.13 to 2.68 ppm, nickel from 0.12 to 1.21 ppm, arsenic from 0.005 to 0.091 ppm, and copper from 0.22 to 0.85 ppm. The paper orders the mean concentrations as lead (Pb) > chromium (Cr) > nickel (Ni) > Cu > arsenic (As).

Methods (brief)

The authors collected 25 unbranded whitening creams from three Karachi markets and stored them at room temperature before analysis. One gram of oven-dried cream was digested with concentrated nitric acid, filtered, diluted to 50 mL with deionized water, and analyzed for Pb, Ni, Cr, As, and Cu using Merck Super Nova60 kits. Each sample was measured in triplicate and reported as means with dispersion statistics.

Implications

Certification: Provides Pakistan-market occurrence data for lead, total chromium, nickel, total arsenic, and copper in unbranded whitening creams. Chromium is total Cr; the source does not speciate hexavalent chromium despite discussing its toxicology.

Courses: Useful for explaining how informal or unregulated cosmetic markets can create dermal exposure to heavy metals.

App: Supports the whitening-products page and consumer-product gap tracking for personal-care matrices.

Update history

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