Scope
- Requested mode: fast serial source-page ingest, no synthesis / standards / pooling / design.
- Roots order: mercury deep dive, ingredient sweep, product sweep, Manual Fetch Kimi, seasonal/geographic auto-fetch, Manual Resourcing, Manual Fetch Discovery.
- Started root:
raw/Research Pull Mercury Deep Dive(/Volumes/HMI-Library/research-pulls/metal-deep-dive-mercury-hg).
Result
- New source pages committed in this continuation: 2.
- Commits made:
6bf226424(ingest: blechinger2026-methylmercury-neurodevelopment-trvs [fresh] from Research Pull Mercury Deep Dive).19697b379(ingest: kim2019-jeju-shark-metals [fresh] from Research Pull Mercury Deep Dive).
- Source pages created:
wiki/sources/blechinger2026-methylmercury-neurodevelopment-trvs.md.wiki/sources/kim2019-jeju-shark-metals.md.
- Routing audit for the Blechinger source exited 0:
4272product-source rows generated overall,13unresolved targets,1021malformed source rows,0blocking. The new Blechinger row inrouting_malformed.csvis advisory only for intentionally emptyproducts/ingredients. - Routing audit for the Kim source exited 0:
4273product-source rows generated overall,13unresolved targets,1021malformed source rows,0blocking. The Kim source added1fish-marine-predatoryproduct-route row and did not appear inrouting_unresolved.csvorrouting_malformed.csv. - Stop reason: paper-internal data-integrity issue in the next new candidate PDF.
Previous Stopper Already Surfaced
Candidate PDF:
raw/Research Pull Mercury Deep Dive/Fish marine non-predatory sardines anchovies salmon cod/JECFA methylmercury/Karjalainen__EstimatedIntake_FinalDraft_2012.pdf
SHA-256:
f5b61d4bb4d58f842211949df2ae90d2161dd95e7b83cb5a9c9466257137160b
Prior finding: the artifact appears incomplete/corrupt. It starts at 1. Introduction, lacks a title page, author list, DOI, and publication venue, and rendered pages around Table 1, Table 2, Figure 1, Figure 2, and Figure 3 show captions without the required table/figure bodies. No source page was written for this artifact.
Current Stopper
Candidate PDF:
raw/Research Pull Mercury Deep Dive/Fish marine non-predatory sardines anchovies salmon cod/Codex mercury fish/10-1007-s12011-021-03064-8.pdf
Identity:
- DOI:
10.1007/s12011-021-03064-8. - SHA-256:
521602b29d1bf3340fc3327555a19ffc410ac6a35ab2d07b6a782fba8bfdb166. - Title:
Metals in Wild and Cultured Dicentrarchus labrax (Linnaeus, 1758) from Fish Markets in Sinop: Consumer's Health Risk Assessment. - Authors: Levent Bat, Fatih Sahin, Md. Simul Bhuyan, Elif Arici, Aysah Oztekin.
Identity / duplicate checks performed:
- DOI grep for
10.1007/s12011-021-03064-8and DOI-slug grep for10-1007-s12011-021-03064-8found no existingwiki/sources/page. - Raw-handle grep for
RPHG_10-1007-s12011-021-03064-8found no existing source page. - Checksum grep for
521602b29d1bf3340fc3327555a19ffc410ac6a35ab2d07b6a782fba8bfdb166found no existing source page. - Proposed cite-key greps for
bat2022-metals-seabass-sinopandbat2022-metals-dicentrarchus-labrax-sinopfound no existing source page.
Data-integrity issue:
- Table 1 reports cultured European seabass Cu as
0.27 mg/kg wet wt.; Figure 1 monthly cultured Cu bars are also visually centered around this magnitude. - The methods give infant fish intake as
13 g/day, infant body weight as10 kg, and the EDI formula as concentration times fish intake divided by body weight. - Using the paper’s own Table 1 concentration, the cultured-Cu infant EDI should be approximately
3.51E-04 mg/kg body wt./day(0.27 mg/kg * 0.013 kg/day / 10 kg). - Table 2 instead reports cultured-Cu infant EDI as
3.079E-03, and the corresponding EWI as2.2E-02. The expected EWI from the paper’s concentration is about2.46E-03. - Table 2’s cultured-Cu children and adults rows,
2.452E-04and1.596E-04, are consistent with the0.27 mg/kg wet wt.concentration. The inconsistency appears localized to the cultured-Cu infant EDI/EWI row and downstream risk calculations. - Table 3 reports cultured-Cu infant THQ as
7.70E-02; using the paper’s4E-02Cu reference dose and the concentration-consistent infant EDI gives about8.8E-03. The reported cultured-infant HI (8.45E-01) therefore appears to include the elevated Cu infant THQ.
Disposition:
- I stopped before writing a
wiki/sources/page for this Bat 2022 candidate, before appending it todata/evidence/audit-queue.csv, before running a source-route audit for it, and before committing any Bat 2022 ingest artifact. - Suggested queue disposition: send the Bat 2022 PDF to Claude/human audit for whether to ingest exact source-reported values with an explicit arithmetic-warning note, exclude the affected risk-calculation cells, or replace with a corrected article version if one exists.
Current Stopper - HJBC Canned Fish Mercury Paper
Candidate PDF:
raw/Research Pull Mercury Deep Dive/Fish marine non-predatory sardines anchovies salmon cod/Codex mercury fish/10-15671-hjbc-778023.pdf
Identity:
- DOI:
10.15671/hjbc.778023. - SHA-256:
2b9e932e3aeb1bbb353cd2f90f6cde4d26ab3c2144b7016984a2a28f85db15f2. - Title:
Validation of Determination by Icp-Oes Method of Mercury Residual Levels in Meat of Canned Fish Put up for Sale in Turkey. - Authors: Fatma Hepsag and Tefide Kizildeniz.
Identity / duplicate checks performed:
- DOI grep for
10.15671/hjbc.778023and DOI-slug grep for10-15671-hjbc-778023found no existingwiki/sources/page. - Raw-handle grep for
RPHG_10-15671-hjbc-778023found no existing source page. - Checksum grep for
2b9e932e3aeb1bbb353cd2f90f6cde4d26ab3c2144b7016984a2a28f85db15f2found no existing source page. - The PDF has
10pages, file size530481bytes, and no encryption.
Data-integrity issue:
- The abstract states that recovery experiments used two concentration levels,
30and50 mg kg-1. Rendered Table 2 instead labels the recovery levels as0.5 ppm Hgand0.3 ppm Hg, with achieved concentration means0.471 mg kg-1and0.295 mg kg-1. - The methods state a total of
375canned fish samples, with skipjack tunan=90, bluefin tunan=95, yellowfin tunan=90, and albacore tunan=100. The results narrative later says that, “from the sample of102canned fish samples,” no sample exceeded the Turkish Food Codex limit. The source does not reconcile102against375. - The abstract states that only
4.8%of investigated samples were detected at a detectable mercury level and that1.3%exceeded the FAO/WHO0.5 mg kg-1recommendation. Table 4 then gives species-level mean/minimum/maximum mercury values for four tuna groups, but it does not state whether these are all samples, detected-only samples, or another subset. - The results text says “Table 3 shows results obtained for Hg in
375samples,” but rendered Table 3 is a certified-reference-material uncertainty table, not a sample-results table. The occurrence table is rendered as Table 4. - Table 4 reports, for example, canned skipjack tuna mean
0.381 mg kg-1, standard deviation0.264 mg kg-1, standard error0.063 mg kg-1, minimum0.09 mg kg-1, and maximum0.66 mg kg-1. The narrative immediately below reports skipjack as0.381 +/- 0.005 mg kg-1 ww, bluefin as0.274 +/- 0.005, yellowfin as0.173 +/- 0.005, and albacore as0.079 +/- 0.005, which does not match Table 4’s standard deviations or standard errors. - The results narrative reports the “smallest Hg” as
0.046 +/- 0.845 mg kg-1 wwand the “highest value of Hg” as0.382 +/- 0.153 mg kg-1 ww; those summary pairs do not reconcile with Table 4’s minimum/maximum values (<LOQto0.66 mg kg-1) or its species means. - The discussion states that the highest mercury level determined in the study was
45.33 ug g-1while also saying detected values were lower than recommended acceptable limits.45.33 ug g-1equals45.33 mg kg-1, which conflicts with Table 4’s maximum0.66 mg kg-1and with the claim that levels were below recommended limits.
Disposition:
- I stopped before writing a
wiki/sources/page for this HJBC candidate, before appending it todata/evidence/audit-queue.csv, before running a source-route audit for it, and before committing any HJBC ingest artifact. - Suggested queue disposition: send the PDF to Claude/human audit for whether it can be ingested with exact source-reported values and a prominent contradiction note, whether only method-validation context should be retained, or whether a corrected article/source table exists.