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Heavy Metal Index

Assessment of heavy metal and nitrate contamination in canned products from local markets in Baghdad

Overview

This study measured heavy metals and nitrate in canned products sold in Baghdad markets, including canned pineapple and fruit cocktail.

Key numbers

Source units are mg/100 g on a dry-weight basis (samples dried at 75 °C; dry-solids percentages reported per row in Tables 1 and 2). Two product categories are within the scope of this page: canned pineapple slices and canned fruit cocktail.

Canned pineapple slices (Thai 16.7% dry solids / Chinese 19.5% dry solids):

  • Pb 0.21 Thai, 0.30 Chinese.
  • Cd 0.00 in both origins.
  • Co 0.01 Thai, 0.00 Chinese.
  • NO3 39.8 Thai, 44.6 Chinese.
  • Mn: the source is internally inconsistent. The body-text paragraph and abstract state “1.01 to 2.37 mg/100g for the Thai and Chinese products, respectively”; Table 2 row for pineapple shows Mn 1.01 Thai and Mn 0.30 Chinese. The Table 2 value (0.30 for Chinese) is preferred for downstream routing because the 2.37 figure in the prose matches an unrelated mushroom row, suggesting a transcription slip in the body text and abstract.
  • Fe 12.5 Thai, 0.34 Chinese.
  • Zn 7.67 Thai, 2.62 Chinese.
  • Cu 2.08 Thai, 0.25 Chinese.

Canned fruit cocktail (chopped fruit; Malaysian 15.2% dry solids / Thai 18.8% dry solids):

  • Pb 0.12 Malaysian, 0.28 Thai.
  • Cd 0.00 in both origins.
  • Co 0.00 in both origins.
  • NO3 28.3 Malaysian, 38.6 Thai.
  • Mn 0.54 Malaysian, 0.24 Thai (body text); Table 2 row for fruit-cocktail shows Mn 0.12 Malaysian and 0.28 Thai, another body-text vs Table 2 disagreement. Both pairs are reported here for transparency.
  • Fe 0.56 Malaysian, 0.77 Thai.
  • Zn 1.83 Malaysian, 0.95 Thai.
  • Cu 0.66 Malaysian, 0.23 Thai.

Methods

Heavy metals (Pb, Cd, Co, Mn, Fe, Zn, Cu) were measured by atomic absorption spectrophotometry per AL-Swaidan (1988); the instrument was calibrated with element-specific standard solutions and re-zeroed every ten readings. Sample preparation: heterogeneous canned contents were homogenised with a food mixer, dried at 75 °C in an electric oven, ground in a dry porcelain mortar, and reported on a dry-weight basis. Digestion: 2 g of dry sample placed in a 200 ml glass flask with 10 ml nitric acid, gradually heated at 250 °C for 1 h, with repeated additions of 5 ml concentrated acid until the sample solution became clear, then quantitatively transferred to volumetric flasks. Nitrate and nitrite were extracted from 105 g of dried sample in 50 ml deionized water (shaker, 2 h, Whatman No. 1 filtration) and measured with a nitrite-nitrate selective electrode (range 0.1 to 62000 ppm; pH 2 to 11; reproducibility 2 %) calibrated against potassium nitrate and nitrite standards, per Kharazi et al. (2021).

Implications

The source contributes country-of-origin-stratified occurrence values for canned pineapple slices and canned fruit cocktail sold in Baghdad markets. Units are mg/100 g on a dry-weight basis; downstream routing must preserve both the unit and the dry-weight basis (or convert explicitly using the reported dry-solids percentages) before comparison with regulatory limits or other studies reporting wet-weight ppb. The paper does not measure arsenic, mercury, nickel, aluminium, chromium, tin, or other HMTc-priority analytes.

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