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Heavy Metal Index

Determination of Physicochemical Properties and Toxic Heavy Metals Levels in Honey Samples from West of Libya

Source

Salama et al. measured physicochemical properties and toxic metals in 24 bee-honey samples from eight locations in western Libya.

Page snapshot
Cited by7 pages
Metals measured4
Evidence tierA
Year2019

Overview

Salama et al. measured physicochemical properties and toxic metals in 24 bee-honey samples from eight locations in western Libya. The paper is direct honey occurrence evidence for lead, cadmium, mercury, and arsenic, reported as location-level means in mg/kg. Lead was the dominant toxic-metal signal, with location means from 2.42 to 10.98 mg/kg.

Key numbers

Table 2 reports all toxic-metal concentrations in mg/kg honey.

Location codePbCdHgAs
GR7.60 +/- 0.360.133 +/- 0.0140.056 +/- 0.010.018 +/- 0.00
BL10.98 +/- 0.520.141 +/- 0.0120.021 +/- 0.040.014 +/- 0.01
MS9.61 +/- 0.450.129 +/- 0.0040.039 +/- 0.030.011 +/- 0.02
RH3.67 +/- 0.390.150 +/- 0.0300.098 +/- 0.020.013 +/- 0.00
AB5.31 +/- 0.570.125 +/- 0.0250.081 +/- 0.020.014 +/- 0.01
AD6.32 +/- 0.410.133 +/- 0.0140.048 +/- 0.010.006 +/- 0.00
TC2.42 +/- 0.260.142 +/- 0.0140.014 +/- 0.030.010 +/- 0.03
TE8.10 +/- 1.580.125 +/- 0.0000.100 +/- 0.040.012 +/- 0.04

The abstract summarizes ranges as Pb 2.42-10.98 mg/kg, Cd 0.125-0.150 mg/kg, Hg 0.021-0.10 mg/kg, and As 0.006-0.018 mg/kg. Table 2 includes a lower Hg location mean of 0.014 mg/kg for TC, so the table range is 0.014-0.100 mg/kg. Essential-element means were also reported: potassium 1120.1-1980.6 mg/kg, sodium 506.8-804.6 mg/kg, and calcium 923.92-1117.5 mg/kg in the abstract; Table 2 includes an MS calcium mean of 1133.8 mg/kg.

Methods (brief)

The study collected three honey samples from each of eight western Libya locations. Samples were stored in glass jars at 4 degrees C. For metal analysis, 1 g honey was digested with nitric acid and hydrogen peroxide in a microwave unit. Sodium, potassium, and calcium were measured by flame photometer, while Pb, Cd, Hg, and As were measured by atomic absorption spectroscopy.

Implications

Certification: This is routeable occurrence evidence for honey, especially for lead and cadmium. Values are reported on a honey-as-sold basis in mg/kg and should not be mixed with ug/kg data without unit conversion.

Courses: The paper illustrates how honey can be used as a local environmental-contaminant matrix and how lead findings can dominate a toxic-metal profile.

App: The honey ingredient/product profile can use this source as non-US context for Pb, Cd, Hg, and total arsenic occurrence.

Microbiome (if applicable): Not addressed.

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Verification notes

The PDF title, authors, DOI, year, journal, methods, and Table 2 values were read from the auto-fetched PDF. The paper reports total arsenic and mercury by atomic absorption spectroscopy; it does not provide inorganic arsenic or methylmercury speciation.

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