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Heavy Metal Index

Total Concentration of Arsenic in Commercial Infant/Toddler Food: A Preliminary Study in Libya

Overview

Vincevica-Gaile and colleagues measured total arsenic in 36 commercial infant/toddler food samples purchased in Libya, grouped by label-declared cereal mixture, wheat, or rice composition. The highest average concentrations were reported in rice-containing infant/toddler foods, but the paper measured total arsenic only and did not speciate inorganic arsenic.

Key numbers

The study used NIST SRM 1568a rice flour as reference material. For arsenic, the reference value was 0.29 +/- 0.03 mg/kg, the detected mean was 0.22 +/- 0.03 mg/kg, recovery was 76%, and the instrumental LOD was 0.02 micrograms/L.

Table 2 reports total arsenic in infant/toddler foods containing mixed cereals:

OriginNRangeMean/median
Libya30.05 to 0.17 mg/kg0.11 mg/kg
Turkey20.19 to 0.27 mg/kg0.23 mg/kg
France10.15 mg/kg0.15 mg/kg
Egypt10.16 mg/kg0.16 mg/kg
Overall ITF-mix70.05 to 0.27 mg/kg0.16 mg/kg

Table 3 reports total arsenic in wheat-containing infant/toddler foods:

OriginNRangeMean/median
Turkey80.04 to 0.25 mg/kg0.14 / 0.16 mg/kg
Oman40.09 to 0.22 mg/kg0.16 / 0.17 mg/kg
Egypt30.29 to 0.33 mg/kg0.32 / 0.33 mg/kg
Germany20.08 to 0.14 mg/kg0.11 mg/kg
Tunisia10.20 mg/kg0.20 mg/kg
Overall ITF-wheat180.04 to 0.33 mg/kg0.19 mg/kg

Table 4 reports total arsenic in rice-containing infant/toddler foods:

OriginNRangeMean/median
Turkey70.15 to 0.35 mg/kg0.22 / 0.21 mg/kg
France30.15 to 0.39 mg/kg0.24 / 0.20 mg/kg
Libya10.16 mg/kg0.16 mg/kg
Overall ITF-rice110.15 to 0.39 mg/kg0.21 / 0.19 mg/kg

The authors report that country-of-origin differences were significant for ITF-wheat (P < 0.004) but not for ITF-mix (P = 0.34) or ITF-rice (P = 0.72).

Methods (brief)

Infant/toddler food samples were purchased from supermarkets in Sabha, Tripoli, and Benghazi, Libya. The authors grouped samples as cereal mixture (n = 7), rice-containing (n = 11), and wheat-containing (n = 18) based on product labels and country of production. Samples were dried at 90 degrees C for 48 h, digested from 0.2 g dry mass with nitric acid and hydrogen peroxide in a Mars5 microwave digester, brought to 50 mL, and analyzed for total arsenic by ICP-MS.

Update history

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CommitDateChangeDescription
b01ec52c32026-08-04major1 section added
3171d069e2026-08-02major1 section added
90a2f9a382026-07-30major1 section added and 1 removed; narrative text revised
eaa8eeeed2026-07-27major1 section added
50de6ab212026-07-27minorNarrative text revised