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Heavy Metal Index

Single-Chamber Microbial Fuel Cell for Cr(VI) Detection in Wastewater

Wang et al.

Overview

Wang et al. (2025) develop a single-chamber microbial fuel cell (MFC) as a biosensor for the detection of hexavalent chromium (Cr(VI)) in wastewater. The MFC exploits the inhibitory effect of Cr(VI) on microbial electro-activity to generate a quantitative signal proportional to Cr(VI) concentration.

Key numbers

LOD: 0.0075 mg/L (7.5 µg/L, or 7.5 ppb) for Cr(VI) in wastewater. This is below typical Cr(VI) industrial discharge limits but above drinking water guidelines for total chromium (WHO: 50 µg/L total Cr) — the LOD is relevant for monitoring rather than compliance in this context.

Note: this sensor detects Cr(VI) specifically (hexavalent chromium), not total chromium. This is the correct speciation for Cr(VI) detection; total Cr must never be treated as Cr-VI. CC BY license.

Methods (brief)

MFC-based bioelectrochemical sensor. Cr(VI) inhibits microbial metabolism, reducing power output measurably. Environmental wastewater matrices. Not validated in food matrices. LOD 7.5 µg/L is reasonable for wastewater monitoring.

Implications

Testing: Cr(VI) is an HMT&C analyte (the program tracks Cr-VI, not total Cr). MFC-based sensors are an interesting emerging approach for environmental Cr(VI) screening, though ICP-MS with appropriate sample preparation remains the standard for food matrix Cr(VI) quantification.

Update history

No substantive edit history is available in this build. The full commit record is available in git.