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Jackson et al. 2012 — Arsenic in Organic Brown Rice Syrup

This landmark 2012 study established that organic brown rice syrup (OBRS), widely used as a sweetener in health-food products and toddler formulas, introduces substantial inorganic arsenic. HPLC-ICP-MS speciation; dry weight unless noted.

Key numbers

Organic brown rice syrup (tAs, ng/g dry weight):

SampletAs (ng/g dw)iAs (% of total)DMA (% of total)
OBRS A lot 178 ± 684%12%
OBRS A lot 294 ± 889%7%
OBRS B136 ± 3~80% est.
OBRS C406 ± 651%46%

Toddler infant formulas with OBRS (reconstituted, µg/L):

Formula typeiAs (µg/L)DMA (µg/L)
Dairy-based with OBRS8–919–26
Soy-based with OBRS15–2534–40

Formulas without OBRS: tAs 2–12 ng/g (much lower).

Cereal bars containing OBRS (ng/g dry weight): Range 23–128 ng/g tAs; >50% iAs in 11 of 12 speciated bars; individual bar iAs up to 4 µg per bar.

Energy products with OBRS (ng/g dry weight): 84–171 ng/g tAs; one product 100% iAs; iAs per 30-g serving: 2.5–2.7 µg.

Methods

HPLC-ICP-MS speciation for As species. Dry weight except reconstituted formulas (µg/L). 15 infant formulas, 2 toddler formulas with OBRS, 29 cereal bars, 3 energy products. University of New Hampshire/Dartmouth.

Key finding: OBRS is predominantly iAs (51–89%), unlike whole brown rice where organic arsenic forms are more balanced. The syrup concentrates the inorganic fraction.

Implications

Certification: Toddler formulas with OBRS (soy-based) reconstituted to 15–25 µg/L iAs — substantially above current FDA guidance of 10 µg/L for drinking water and high relative to the 100 ppb (µg/kg) FDA action level for infant rice cereal. OBRS in infant food should be flagged as a source-specific risk driver.

App: Flag “brown rice syrup,” “organic brown rice syrup,” “rice syrup” in ingredient lists as a marker for elevated iAs, especially in toddler formulas and cereal bars.

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Page history

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